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It seems that the Xbox Scarlett will be the next step in bridging the gap between console and PC players - and that doesn't just refer to technical prowess. Spencer and the Xbox team have been adamant about allowing players to play their games wherever they want and with whomever they want. Part of that gap has been filled with the Xbox Play Anywhere initiative, in which all first-party Xbox gamesare playable on both PC and Xbox One with cross-play support. That, coupled with the Xbox Game Pass (a subscription service that includes every Microsoft Studios-published game on the day of release), is a significant leap in closing that chasm.

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Nitrogen fixation and reduction at boron

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23 Feb 2018: Vol. 359, Issue 6378, pp. 896-900 DOI: 10.1126/science.aaq1684
Marc-André Légaré
Institute for Inorganic Chemistry, Julius-Maximilians-Universität Würzburg, Am Hubland, 97074 Würzburg, Germany. Institute for Sustainable Chemistry Catalysis with Boron, Julius-Maximilians-Universität Würzburg, Am Hubland, 97074 Würzburg, Germany.
Guillaume Bélanger-Chabot
Institute for Inorganic Chemistry, Julius-Maximilians-Universität Würzburg, Am Hubland, 97074 Würzburg, Germany. Institute for Sustainable Chemistry Catalysis with Boron, Julius-Maximilians-Universität Würzburg, Am Hubland, 97074 Würzburg, Germany.
Rian D. Dewhurst
Institute for Inorganic Chemistry, Julius-Maximilians-Universität Würzburg, Am Hubland, 97074 Würzburg, Germany. Institute for Sustainable Chemistry Catalysis with Boron, Julius-Maximilians-Universität Würzburg, Am Hubland, 97074 Würzburg, Germany.
Eileen Welz
Institute for Physical and Theoretical Chemistry, Julius-Maximilians-Universität Würzburg, Emil-Fischer-Strasse 42, 97074 Würzburg, Germany.
Ivo Krummenacher
Institute for Inorganic Chemistry, Julius-Maximilians-Universität Würzburg, Am Hubland, 97074 Würzburg, Germany. Institute for Sustainable Chemistry Catalysis with Boron, Julius-Maximilians-Universität Würzburg, Am Hubland, 97074 Würzburg, Germany.
Bernd Engels
Institute for Physical and Theoretical Chemistry, Julius-Maximilians-Universität Würzburg, Emil-Fischer-Strasse 42, 97074 Würzburg, Germany.
Holger Braunschweig
Institute for Inorganic Chemistry, Julius-Maximilians-Universität Würzburg, Am Hubland, 97074 Würzburg, Germany. Institute for Sustainable Chemistry Catalysis with Boron, Julius-Maximilians-Universität Würzburg, Am Hubland, 97074 Würzburg, Germany.

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Boron learns to give back to nitrogen

Although diatomic nitrogen is famously inert, a variety of transition metals can bind to it through a process termed backbonding. As the nitrogen weakly shares its own electrons, some electrons from the metal reach back out to it. Nonmetals would not seem to have the capacity for this type of bonding, but now Légaré show that conventionally electron-deficient boron can be coaxed into it (see the Perspective by Broere and Holland). The authors treated boron-based precursors with potassium under a nitrogen atmosphere to produce several compounds with sandwiched dinitrogen between two boron centers in reduced motifs reminiscent of metal complexes.

, this issue p. 896 ; see also p. 871

Abstract

Currently, the only compounds known to support fixation and functionalization of dinitrogen (N) under nonmatrix conditions are based on metals. Here we present the observation of N binding and reduction by a nonmetal, specifically a dicoordinate borylene. Depending on the reaction conditions under which potassium graphite is introduced as a reductant, N binding to two borylene units results in either neutral (BN) or dianionic ([BN]) products that can be interconverted by respective exposure to further reductant or to air. The N isotopologues of the neutral and dianionic molecules were prepared with N-labeled dinitrogen, allowing observation of the nitrogen nuclei by N nuclear magnetic resonance spectroscopy. Protonation of the dianionic compound with distilled water furnishes a diradical product with a central hydrazido BNH unit. All three products were characterized spectroscopically and crystallographically.

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Nitrogen fixation and reduction at boron

By Marc-André Légaré , Guillaume Bélanger-Chabot , Rian D. Dewhurst , Eileen Welz , Ivo Krummenacher , Bernd Engels , Holger Braunschweig

Honeycutt starred at UCLA and played for the Sacramento Kings

Honeycutt, a 6-foot-8 forward from Sylmar, just north of Los Angeles, played two seasons at UCLA from 2009-2011 and earned first-team All-Pac 12 honors in his sophomore season. He then declared for the NBA draft and was selected by Sacramento in the second round (35th overall pick) in 2011.

He played minimally for the Kings and was eventually traded to Houston in 2013. He never played for the Rockets, and in August, 2013, he moved his playing career overseas, starting with Ironi Nes Ziona in Israel. For the past few years, he had bounced back and forth between Khimki and Anadolu Efes in Turkey.

Honeycutt’s coach at Khimki, Giorgios Bartzokas, was too overwhelmed to comment, saying“I am sorry I cannot talk right now, I am really sad.”

“I am sorry i cannot talk right now, i am really sad” GBartzokas. Tyler Honeycutt, massa jove per morir.

— Víctor Lavagnini (@victorlavagnini)

Many NBA players — both current and past — expressed their thoughts on Twitter.

Still can’t believe this… Rest In Peace to my brother Tyler Honeycutt

— That Boy Jrue (@Jrue_Holiday11)

hurt by the news, glad no one else was injured, but ultimately sad to say, rest in peace to my basketball brother tyler honeycutt…

— Solomon Hill (@solohill)

R.I.P. Tyler Honeycutt

— Terrence Ross (@TFlight31)

RIP Tyler Honeycutt🙏🏾

Prayers up for his family and friends. Rest easy bro!

— DeMarcus Cousins (@boogiecousins)

RIP tyler honeycutt

— Spencer Dinwiddie (@SDinwiddie_25)

Wow. RIP to Tyler HoneyCutt. Former Teammate Good Friend. Thoughts and Prayers to His Family!

— Jason Thompson (@jtthekid)

My prayers go out to Tyler Honeycutt never know what ppl are going thru.

— Joe Crawford (@JoeCrawford5)

Rest Easy Tyler Honeycutt.. prayers up for him and family.. devastating.. just saw him yesterday..

— Quincy Pondexter (@QuincyPondexter)

Rest Easy Young King …Tyler Honeycutt … Extremely Sad News..

— DaJuan Summers (@DSummersTime)

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Dear MoneyToken Community,

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Results of token distribution polls

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